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Article
Publication date: 10 July 2019

Adam Gnatowski and Agnieszka Kijo-Kleczkowska

The main purpose of polymeric mixtures manufacturing is wish to eliminate or reduce drawbacks which polymers are characterised by and also to strive for reduction of the price of…

Abstract

Purpose

The main purpose of polymeric mixtures manufacturing is wish to eliminate or reduce drawbacks which polymers are characterised by and also to strive for reduction of the price of expensive polymers with particular very precious properties by mixing them with cheaper polymers but without significant deterioration of their properties. In the work some investigation results have been presented for PA6 which is miscible in viscoelastic state with polymer, with ability to create physical bounds with substances of inorganic as well as organic origins. For this purpose, polyvinylpyrrolidone (PVP) has been used with law molecular weight (10 ± 2,5 thousand). The functionalactive material was prepared with sharp tuning sorption ability across physical modification polycapramide mixed from bipolar polyvinylpyrrolidone in batch – free state, which characterises high ability complex. In the paper, some results of chosen properties of PA with the addition of polyvinylpyrrolidone (PVP) have been presented. In chance of mixing PA6 with PVP forms solution PVP in PA6, to which proper are large intermolecular influence, in this case hydrogen bond. It is possible to foresee that under the influences of large tangent stresses and intermolecular interaction colloidal solution PVP in PA forms with sure homogeneity, after cooling of it the inversion of winding phases is not noticeable In the mixtures on the basis of such polymers the intermolecular interactions occur, and they differently influence parameters of the modified materials. Conducted investigations have proved opportunity of physical modification of PA6 during mixing, in viscoelastic state, with polyvinylpyrrolidone. The modified polymer has dielectric properties and a reduced susceptibility to water absorption. It can be used as an insulation material, in all industrial sectors, including the energy sector.

Design/methodology/approach

For examinations, the following mixtures were made out: PA 99%/PVP 1%, PA 98%/PVP 2%, PA 90%/PVP 10%. Making mixtures out was begun with weighing elements out on numerical Sortorius AG GO TTINGEN scales and CAS MODEL: SW-1 (PA, PVP). Next elements of mixture were mixed with themselves mechanically. The process of drying was carried out in the ZELMET drier with the thermal kc-100/200 chamber in the temperature 80 °C for 12 h. The process of mixing up was carried out in the arrangement plasticising injections moulding machine of the voluted KRAUSS MAFFEI company KM 65-1600C1 (D screw = 30 mm and the L = 27D, the nozzle about d = 4 mm and the l = 2d) at the following parameters: is the nozzle temperature 230 °C, the speed of turnovers of the screw 210 obr/min. Granulated product of mixtures were get on the rotor grinder. Samples for examinations were made on the computer-operated injection moulding machine of type of KM 65-1600C1 of the KRAUSS MAFFEI company. The conditions which complement the homogeneity of a mixture – these include mixing processes with high shear stresses with the range of temperatures for viscoelastic state for the individual polymers. Such conditions are met by multiple mixing in the injection machine cylinder with extended perpetual screw length (L/D = 25 ÷ 42). Permanent conditions of injecting samples for the research on physical properties were the following: nozzle temperature – 230°C; worm area I temperature – 190°C; worm area II temperature – 210°C; worm area III temperature – 230-245°C, mould temperature 40°C, injection pressure – 60 MPa, clamping time – 5 s, cooling time – 30 s The research on chosen physical properties of getting polymer materials was carried out: hardnesses on hardness testing machine, impact resistance by Charpy’s method, mechanical properties while tension over the endurance machine the INSTON with tension speed of 90 mm/min, softening point by Vicat’s method was determined using testing machine type HAAKE N8, the investigation of DSC method and DMTA method using testing machine type Netzsch, water absorbing power test. The research on the structure was also carried out on the optical microscope type NIKON ECLIPSE E200.

Findings

In the paper, for the physical modification of PA 6, the polyvinylpyrrolidone (PVP) – amorphous polymer which is capable of ionisation and creation of complexes with the transition of the charge with many electrophilic compounds and also proton donors have been used. PVP does not change into the viscoelastic state but it is easily soluble in organic and inorganic solvents and the best in water. Its characteristic is high sorption capacity. As a result of ionisation changes PVP preserve the conformation changes. In case of mixing of polar PA6 polymers with PVP, a PVP solution is being created in PA, to whom big intermolecular interactions are proper for, in it hydrogen bonds. Reducing of polarity occurs of both polymers as a result of hydrogen bonds in created macromolecules. Macromolecule so they are interfering easily in fused condition creating the mixture about reliable homogeneity. An effect is applying to mixing with PA6 in case of dissolving PVP in the PA6 stop under the influence of big adjacent tensions in screw extruder what is calling changes of the supermolecular structure and properties of the material after chilling of stop in the form during injecting. The resultant homogeneous mixture is marked by one reflex narrowed in comparison with output PA6 of melting visible on DSC thermogram with moving to the page of higher tmmax temperatures. PA6/PVP mixtures are also providing effects of examinations about the homogeneity with DMTA method which shows results that the mixture is marked by one reflex of mechanical losses on the plot from (Tg) from the maximum at bigger than PA6 Tg (about 10 ÷ 15°C), and it is possible at the same time to reason that the mixture has not very thick frictional network as a result of the exchange of intermolecular bonds what is displayed itself in the increase in Tg intensity. The results of investigations show that PA with PVP additions create more stable material with visible homogeneity (due to strong intermolecular interactions) which is characterised by satisfactory mechanical properties which insignificantly differ from PA6 properties, but which shows higher deformability and sorptive power.

Originality/value

The results of investigations show that PA with PVP additions create more stable material with visible homogeneity (due to strong intermolecular interactions) which is characterised by satisfactory mechanical properties which insignificantly differ from PA6 properties, but which shows higher deformability and sorptive power. The modified polymer has dielectric properties and a reduced susceptibility to water absorption. It can be used as an insulation material, in all industrial sectors, including the energy sector.

Details

International Journal of Numerical Methods for Heat & Fluid Flow, vol. 30 no. 4
Type: Research Article
ISSN: 0961-5539

Keywords

Article
Publication date: 7 June 2019

Adam Gnatowski, Agnieszka Kijo-Kleczkowska, Rafał Gołębski and Kamil Mirek

The issues concerning the prediction of changes in properties of polymer materials as a result of adding reinforcing fibers are currently widely discussed in the field of polymer…

Abstract

Purpose

The issues concerning the prediction of changes in properties of polymer materials as a result of adding reinforcing fibers are currently widely discussed in the field of polymer material processing. This paper aims to present strengths and weaknesses of composites based on polymer materials strengthened with fibers. It touches upon composite cracking at the junction of a matrix and its reinforcement. It also discusses the analysis of changes in properties of chosen materials as a result of adding reinforcing fibers. The paper shows improvement in the strength of polymer materials with fiber addition, which is extremely important, because these types of composites are used in the aerospace, automotive and electrical engineering industries.

Design/methodology/approach

Comparing the properties of matrix strength with fiber properties is practically impossible. Thus, fiber tensile strength and composite tensile strength shall be compared (González et al., 2011): tensile (glass fiber GF) = 900 [MPa], elongation ΔL≈ 0; yield point (polyamide 66) = 70−90 [MPa], elongation Δ[%] = 3,5-18; tensile (polyamide 66 + 15% GF) = 80-125 [MPa], elongation Δ[%] ≈ 0; tensile (polyamide 66 + 30% GF) = 190 [MPa], elongation Δ[%] ≈ 0; yield point (polyamide 6) = 45-85 [MPa], elongation Δ[%] = 4-15; tensile (polyamide 6 + 15% GF) = 80-125 [MPa], elongation Δ[%] ≈ 0; tensile (polyamide 6 + 30% GF) = 95-130 [MPa] elongation Δ[%] ≈ 0. Comparison of properties of selected polymers and composites is presented in Tables 1−10 and Figures 1 and 2. The measurement methodology is presented in detail in the paper Kula et al. (2018). The increase in fiber content (to the extent discussed) leads to the increase in yield strength stresses and hardness. The value of yield strength for polyamide with the addition of fiberglass grows gradually with the increase in fiber content. The hardness of the composite of polyamide with glass balls increases together with the increase in reinforcement content. The changes of these values do not occur linearly. The increase in fiber content has a slight impact on density change (the increase of about 1 g/mm3 per 10 per cent).

Findings

The use of polymers as a matrix allows to give composites features such as: lightness, corrosion resistance, damping ability, good electrical insulation and thermal and easy shaping. Polymers used as a matrix perform the following functions in composites: give the desired shape to the products, allow transferring loads to fibers, shape thermal, chemical and flammable properties of composites and increase the possibilities of making composites. Fiber-reinforced polymer composites are the effect of searching for new construction materials. Glass fibers show tensile strength, stiffness and brittleness, while the polymer matrix has viscoelastic properties. Glass fibers have a uniform shape and dimensions. Fiber-reinforced composites are therefore used to increase strength and stiffness of materials. Polymers have low tensile strength, exhibit high deformability. Polymers reinforced by glass fiber have a high modulus of elasticity and therefore provide better the mechanical properties of the material. Composites with glass fibers do not exhibit deformations in front of cracking. An increase in the content of glass fiber in composites increases the tensile strength of the material. Polymers reinforced by glass fiber are currently one of the most important construction materials and are widely used in the aerospace, automotive and electro-technical industries.

Originality/value

The paper presents the test results for polyethylene composites with 25 per cent and 50 per cent filler coming from recycled car carpets of various car makes. The tests included using differential scanning calorimetry, testing material hardness, material tensile strength and their dynamic mechanical properties.

Details

International Journal of Numerical Methods for Heat & Fluid Flow, vol. 30 no. 6
Type: Research Article
ISSN: 0961-5539

Keywords

Article
Publication date: 28 June 2018

Artur Lach, Andrzej Katunin and Adam Gnatowski

The paper aims to present a design and numerical verification procedure of a composite casing of a microstrip antenna for an aerospace satellite.

Abstract

Purpose

The paper aims to present a design and numerical verification procedure of a composite casing of a microstrip antenna for an aerospace satellite.

Design/methodology/approach

The casing for the microstrip antenna was designed in a form of a laminate shell with variable number of layers of reinforcing fabric. The material properties, both static and dynamic, were determined experimentally and then exported to an environment of numerical analyses. The numerical modal analysis allows optimizing the geometry and lay-up of the casing in such a way that a number of modal shapes occurring in the operational frequency band was significantly reduced, several modal shapes with high displacement in flanges of the casing were eliminated and the values of natural frequencies were increased. A final model of the composite casing was subjected to two types of analyses which simulate typical operation conditions during spacecraft mission. These analyses contained thermomechanical quasi-static analyses with 12 loadcases and thermomechanical shock analyses with 9 loadcases, which simulate various mechanical and temperature conditions.

Findings

Results of the performed analyses were compared with safety margins determined by following requirements to spacecraft vehicles. The obtained results confirm the design feasibility, which allow considering the proposed design during manufacturing of a prototype in further studies.

Practical implications

Moreover, the presented results can be considered as a design methodology guideline, which can be helpful for engineers working in the aerospace industry.

Originality/value

The originality of the paper lies in the proposed design and verification procedure of composite elements subjected to operational loading during a spacecraft mission.

Details

Aircraft Engineering and Aerospace Technology, vol. 90 no. 5
Type: Research Article
ISSN: 1748-8842

Keywords

Article
Publication date: 29 April 2019

Adam Jakubas, Radosław Jastrzębski and Krzysztof Chwastek

The purpose of this paper is to examine the effect of varying compaction pressure on magnetic properties of self-developed soft magnetic composite (SMC) cores. The change in shape…

Abstract

Purpose

The purpose of this paper is to examine the effect of varying compaction pressure on magnetic properties of self-developed soft magnetic composite (SMC) cores. The change in shape of ferromagnetic hysteresis curves has – in turn – the impact on the values of hysteresis model parameters. The phenomenological GRUCAD model is chosen for description of hysteresis curves.

Design/methodology/approach

Several cylinder-shaped cores have been made from a mixture of iron powder and suspense polyvinyl chloride using a hydraulic press with a form and a band with a thermocouple for controlling heat treatment conditions. The only varying parameter in the study is the compaction pressure. The magnetic properties of developed cores have been measured using a computer-acquisition card and LabView software. The obtained hysteresis curves are fitted to the equations of the phenomenological GRUCAD model. This description is compliant with the laws of irreversible thermodynamics. The variations of model parameters are presented as functions of compacting pressure.

Findings

The compaction pressure has a significant impact on magnetic properties of self-developed SMC cores. The paper provides a number of charts useful for checking how the parameters of the hysteresis model are affected.

Research limitations/implications

The present paper is limited to modelling symmetrical loops only. Description of more complex magnetization cycles is postponed to another, forthcoming paper.

Practical implications

The GRUCAD hysteresis model may be a useful tool for the designers of magnetic circuits. Its parameters depend on the processing conditions (in this study – the compaction pressure) of the SMC cores.

Originality/value

Modelling of magnetic properties of SMC cores has been carried so far using some well-known description like Preisach, Takács and Jiles–Atherton proposals. The GRUCAD model has a number of advantages, and it may be a useful alternative to the latter formalism. So far it has been used for description of hysteresis curves in conventional materials like non-oriented and grain-oriented electrical steels. In the present work, it is applied to novel SMC materials.

Details

COMPEL - The international journal for computation and mathematics in electrical and electronic engineering, vol. 38 no. 4
Type: Research Article
ISSN: 0332-1649

Keywords

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